Bonded abrasive article and method of forming

ABSTRACT

An abrasive article having an abrasive body including abrasive grains contained within a bond material, wherein the abrasive grains comprise microcrystalline alumina, and wherein the bond material includes less than about 1.0 mol % phosphorous oxide (P 2 O 5 ), and a ratio measured in mol % between a total content of sodium oxide (Na 2 O) and a total content of potassium oxide (K 2 O) defined by [K 2 O/Na 2 O] having a value greater than about 0.5.

The present application claims priority from U.S. ProvisionalApplication No. 61/249,659 filed Oct. 8, 2009, which application isincorporated by reference herein in its entirety.

BACKGROUND

1. Field of the Disclosure

The following is directed to bonded abrasives and particularly bondedabrasive articles incorporating microcrystalline alumina abrasivegrains.

2. Description of the Related Art

Abrasive tools are generally formed to have abrasive grains containedwithin a bond material for material removal applications. Superabrasivegrains (e.g., diamond or cubic boron nitride (CBN)) or seeded (or evenunseeded) sintered sol gel alumina abrasive grain, also referred tomicrocrystalline alpha-alumina (MCA) abrasive grain, can be employed insuch abrasive tools and are known to provide superior grindingperformance on a variety of materials. The bond material can be organicmaterials, such as a resin, or an inorganic material, such as a glass orvitrified material. In particular, bonded abrasive tools using avitrified bond material and containing MCA grains or superabrasive grainare commercially useful for grinding precision metal parts and otherindustrial components requiring consistent and improved grindingperformance.

Certain bonded abrasive tools, particularly those utilizing a vitrifiedbond material, require high temperature forming processes, oftentimes onthe order of 1000° C. or greater, which can have deleterious effects onthe abrasive grains. In fact, it has been recognized that at suchelevated temperatures necessary to form the abrasive tool, the bondmaterial can react with the abrasive grains, particularly MCA grains,and damage the integrity and reducing the grain sharpness andperformance properties. As a result, the industry has migrated towardreducing the formation temperatures necessary to form the bond materialin order to curb the high temperature degradation of the abrasive grainsduring the forming process.

For example, to reduce the amount of reaction between MCA grain andvitrified bond, U.S. Pat. No. 4,543,107 discloses a bond compositionsuitable for firing at a temperature as low as about 900° C. In analternate approach, U.S. Pat. No. 4,898,597 discloses a bond compositioncomprising at least 40% fritted materials suitable for firing at atemperature as low as about 900° C. Other such bonded abrasive articlesutilizing bond materials capable of forming at temperatures below 1100°C., and in fact, below 1000° C., include U.S. Pat. No. 5,203,886, U.S.Pat. No. 5,401,284, U.S. Pat. No. 5,536,283, and U.S. Pat. No.6,702,867. Still, the industry continues to demand improved performanceof such bonded abrasive articles.

SUMMARY

According to one aspect an abrasive article includes an abrasive bodyhaving abrasive grains contained within a bond material, wherein theabrasive grains comprise microcrystalline alumina, and wherein the bondmaterial comprises less than about 1.0 mol % phosphorous oxide (P₂O₅).The bond material can have a ratio measured in mol % between a totalcontent of sodium oxide (Na₂O) and a total content of potassium oxide(K₂O) defined by [K₂O/Na₂O] having a value greater than about 0.5.

In another aspect, an abrasive article includes an abrasive body havinga porosity of less than about 50 vol % and abrasive grains containedwithin a bond material, wherein the abrasive grains includemicrocrystalline alumina, and wherein the bond material comprises atotal content of alkali oxides less than about 12 mol % and less thanabout 2.0 mol % lithium oxide (Li₂O).

In accordance with yet another aspect, an abrasive article includes anabrasive body having abrasive grains contained within a bond material,wherein the abrasive grains comprise microcrystalline alumina, andwherein the bond material comprises less than about 2.0 mol % lithiumoxide (Li₂O), and less than about 10 mol % boron oxide (B₂O₃).

In still another aspect, an abrasive article includes an abrasive bodyhaving abrasive grains contained within a bond material, wherein theabrasive grains comprise microcrystalline alumina, and wherein the bondmaterial comprises a total content of alkali oxides less than about 12mol %. The abrasive article exhibits a sandblast penetration into theabrasive body of not greater than about 2.2 mm as measured under theconditions measured in a sandblast chamber having a volume of 48 ccusing standard sand under a pressure of 15 psi for about a single cycletime of 10 seconds.

Another aspect includes an abrasive article comprising an abrasive bodyincluding abrasive grains contained within a bond material, wherein theabrasive grains comprise microcrystalline alumina, and wherein the bondmaterial comprises less than about 10 mol % boron oxide (B₂O₃). Theabrasive body further exhibits a sandblast penetration into the abrasivebody of not greater than about 2.2 mm as measured under the conditionsmeasured in a sandblast chamber having a volume of 48 cc using standardsand under a pressure of 15 psi for about a single cycle time of 10seconds.

According to one aspect, a method of forming an abrasive articleincludes mixing abrasive grains comprising microcrystalline alumina witha bond material powder, wherein the bond material powder comprises notgreater than about 15 wt % alkali oxide compounds, and forming themixture into a green article. The method further includes heating thegreen article to a firing temperature of at least about 1100° C. to forman abrasive article having abrasive grains contained within a vitreousbond material.

According to a particular aspect, an abrasive article includes anabrasive body having a porosity of less than about 50 vol % and abrasivegrains contained within a bond material, wherein the abrasive grainscomprise microcrystalline alumina. The bond material comprises a totalcontent of alkali oxides less than about 13 mol % and less than about2.0 mol % lithium oxide (Li₂O). More particularly, the bond material cancontain less than about 12.8 mol %, or less than about 12.6 mol %, oreven less than about 12.4 mol % alkali oxides for the total amount ofmols within the bond material.

BRIEF DESCRIPTION OF THE DRAWINGS

The present disclosure may be better understood, and its numerousfeatures and advantages made apparent to those skilled in the art byreferencing the accompanying drawings.

FIG. 1 includes a flow chart illustrating a method of forming anabrasive article in accordance with an embodiment.

FIG. 2 includes a plot of average power consumption versus materialremoval rate for a sample formed according to an embodiment and aconventional bonded abrasive sample.

FIG. 3 includes a plot of average surface roughness (Ra) versus materialremoval rate for a sample formed according to an embodiment and aconventional bonded abrasive sample.

The use of the same reference symbols in different drawings indicatessimilar or identical items.

DETAILED DESCRIPTION

The following is generally directed to an abrasive article, particularlya bonded abrasive article utilizing abrasive grains contained within abond material. Such abrasive articles are useful in material removalapplications, such as those in various industries for finishing and/orgrinding workpieces. The abrasive articles can be shaped and sized tomake various finishing tools, such as wheels, cones, cup-shapedarticles, hones, and/or stones.

FIG. 1 includes a flow chart illustrating a method of forming anabrasive article in accordance with an embodiment. As illustrated, theprocess is initiated at step 101 by mixing abrasive grains with a bondmaterial powder. In accordance with an embodiment, the abrasive grainscan include an inorganic material, such as an oxide. More particularly,the abrasive grains can include microcrystalline alumina (MCA) grains.

The MCA or sol-gel alumina grains are preferably produced by either aseeded or an unseeded sol gel process. As used herein, the term “sol-gelalumina grits” are alumina grits made by a process comprising peptizinga sol of an aluminum oxide monohydrate so as to form a gel, drying andfiring the gel to sinter it, and then breaking, screening and sizing thesintered gel to form polycrystalline grains made of alpha aluminamicrocrystals (e.g., at least about 95% alumina). In addition to thealpha alumina microcrystals, the initial sol may further include up to15% by weight of spinel, mullite, manganese dioxide, titania, magnesia,rare earth metal oxides, zirconia powder or a zirconia precursor (whichcan be added in larger amounts, e.g. 40 wt % or more), or othercompatible additives or precursors thereof. These additives are oftenincluded to modify such properties as fracture toughness, hardness,friability, fracture mechanics, or drying behavior. Preparation ofsintered sol gel alpha-alumina grains is described in detail elsewhere.Details of such preparations may be found, for example, in U.S. Pat.Nos. 4,623,364, 4,314,827, and 5,863,308, the contents of which arehereby incorporated by reference.

The term MCA grain is defined to include any grain comprising at least60% alpha alumina microcrystals having at least 95% theoretical densityand a Vickers hardness (500 grams) of at least 18 GPa at 500 grams. Thesintered sol gel alpha-alumina grain may contain platelets of materialother than alpha-alumina dispersed among the alpha-aluminamicrocrystals. Generally, the alpha-alumina particles and the plateletsare submicron in size when made in this form. Further details of MCAabrasive grain preparations and MCA abrasive grain types useful in thepresent invention may be found in any one of the numerous other patentsand publications which cite the basic technology disclosed in the U.S.Pat. Nos. 4,623,364 and 4,314,827.

The microcrystalline alumina utilized in the abrasive grains can have anaverage crystallite size of less than 1 micron. In fact, in certaininstances, the microcrystalline alumina can have an average crystallitesize of less than about 0.5 microns, and particularly within a rangebetween about 0.1 and about 0.2 microns.

Additionally, it will be appreciated that the bonded abrasive articlesof embodiments herein may utilize a certain content of secondaryabrasive grains. When secondary abrasive grains are used, such abrasivegrains can provide from about 0.1 to about 97 vol % of the totalabrasive grain of the tool, and more preferably, from about 30 to about70 vol %. The secondary abrasive grains which may be used include, butare not limited to, alumina oxide, silicon carbide, cubic boron nitride,diamond, flint and garnet grains, and combinations thereof.

In reference to the bond material powder, inorganic materials may beutilized, and in particular, inorganic materials that facilitate theformation of a final-formed abrasive article having a vitreous bond.That is, the final-formed bonded abrasive article can have a vitreousbond having a certain content of amorphous phase. In particular, thefinal-formed bonded abrasive article of embodiments herein can have abond material that consists essentially of an amorphous phase.

In particular instances, the bond material powder can include inorganicmaterials, such as oxides. Notably, the bond material powder can includea frit material that is suitable for forming the vitrified final-formedbond material. A frit material can include a powder material formed forma glass, which is formed by firing initially to an elevated temperature(e.g., 1000° C. or greater), cooling, crushing and sizing to yield apowdered material (“a frit”). The frit then may be melted at atemperature well below the initial firing temperature used to make theglass from the raw materials, such as silica and clays.

The following paragraphs denote certain contents and certaincompositions which may be used in the bond material powder. It will beappreciated that reference herein to the particular amounts of certaincompositions in forming the mixture may not necessarily form a finalbond composition in the final-formed abrasive article having the exactsame content of each of the species noted. That is, during the formingprocess, the content of certain species can change such that thefinal-formed bonded abrasive may not necessarily contain the sameamounts of certain species as was initially included in the bondmaterial powder of the initial mixture.

Embodiments herein can utilize a bond material powder having a fritmaterial. Frit material may be formed from oxides such as silica,alkaline oxide compounds, alkaline earth oxide compounds, and acombination thereof. The frit material facilitates suitable forming of avitrified bond material in the final-formed bonded abrasive. Accordingto one embodiment, the bond material powder can include a certaincontent of silica (SiO₂). For example, embodiments herein may utilize abond material powder formed from at least about 50 mol % silica. Inother embodiments, the amount of silica can be greater, such as at leastabout 55 mol %, such as at least about 56 mol %, and particularly withina range between about 55 and about 70 mol % silica.

Additionally, the bond material powder can include a certain content ofalkali oxide compounds, and particularly a low content of such alkalioxides, which may be more prevalent in low-temperature bondcompositions. Alkali oxide compounds are oxide compounds and complexesutilizing alkali species denoted as Group 1A elements in the PeriodicTable, such as lithium oxide (Li₂O), potassium oxide (K₂O), sodium oxide(Na₂O), and a combination thereof.

In accordance with one embodiment, the bond material powder can beformed from not greater than about 14 mol % total alkaline oxidecompounds. In other instances, the bond material powder is formed fromless alkaline oxide compounds, such as on the order of not greater thanabout 13 mol %, not greater than about 12.8 mol %, not greater thanabout 12.6 mol %, not greater than about 12.4 mol %, not greater thanabout 12 mol %, or even not greater than about 11 mol %. Particularembodiments herein may form a bond material powder having a totalcontent of alkaline oxide compounds within a range between about 5 mol %and about 14 mol %, such as between about 8 mol % and about 13 mol %,between about 9 mol % and about 12.8 mol %, or even between about 9 mol% and about 12 mol %.

In particular reference to lithium oxide, the bond material powder cancontain a particularly low content of lithium oxide, which may be moreprevalent in certain low-temperature bond compositions. For example, inembodiments herein, the bond material powder can be formed from lessthan 2.0 mol % lithium oxide. In other instances, the content of lithiumoxide may be less, such as on the order of less than about 1.5 mol %,such as less than 1.0 mol %, such as less than 0.5 mol %. In oneparticular instance, the bond material powder is formed such that it isessentially free of lithium oxide.

The bond material powder can be formed from a particular content ofsodium oxide. For example, embodiments herein may utilize between about2.0 mol % and about 8.0 mol %, such as between about 3.0 mol % and about7.0 mol %.

Additionally, embodiments herein may utilize a particular content ofpotassium oxide, such as within a range between about 2.0 mol % andabout 8.0 mol %, such as between about 3.0 mol % and about 8.0 mol %.

The bond material powder can be formed from a certain content ofalkaline earth oxide compounds. Alkaline earth oxide compounds are oxidecompounds and complexes incorporating divalent species from the alkalineearth elements present in Group 2A of the Periodic Table of Elements.That is, for example, certain suitable alkaline earth oxide compoundscan include magnesium oxide (MgO), calcium oxide (CaO), strontium oxide(SrO), barium oxide (BaO), and a combination thereof. In accordance withone embodiment, the bond material powder used can be formed from notgreater than about 10 mol % total alkaline earth oxide compounds. Inother instances, the content of alkaline earth oxide compounds is less,such as on the order of not greater than about 9.0 mol %, not greaterthan about 8.0 mol %, or even not greater than about 7.0 mol %.Particular embodiments herein may utilize a total content of alkalineearth oxide compounds within a range between about 2.0 mol % and about10 mol %, such as between about 4.0 mol % and about 9.0 mol %.

Of the alkaline earth oxide compounds, magnesium oxide may be present inthe greatest content as compared to the other alkaline earth oxidecompounds within the bond material powder. For example, the bondmaterial powder can be formed from at least about 2.0 mol %, such as atleast 3.0 mol % magnesium oxide. In certain mixtures, the bond materialpowder can contain between about 3.0 mol % and 7.0 mol %, and moreparticularly within a range between about 3.0 mol % and 6.0 mol % ofmagnesium oxide.

The bond material powder can include a certain content of calcium oxide.For example, embodiments herein may utilize a bond material powderformed from at least about 0.5 mol % calcium oxide, such as within arange between about 0.5 mol % and 3.0 mol % calcium oxide.

The bond material powder may contain a certain content of barium oxide.However, the amount of barium oxide can be less than the amount ofmagnesium oxide and/or calcium oxide. Generally, the bond materialpowder contains less than about 2 mol %, such as less than about 1 mol %barium oxide.

According to embodiments herein, the bond material powder can be formedto have a particular content of alumina (Al₂O₃). For example,embodiments herein may utilize a bond material powder formed from lessthan about 13 mol % alumina, such as less than about 12 mol % alumina,or even less than about 11 mol % alumina. Still, certain mixtures canutilize a bond material powder formed from a content of alumina within arange between about 8.0 mol % and about 13 mol %, such as between about8.0 mol % and about 12 mol %.

In addition to the oxide species noted above, the bond material powdercan be formed to have a particular content of phosphorous oxide (P₂O₅),which may be a particularly small amount compared to certainlow-temperature bond compositions. For example, the bond material powdercan be formed from less than 1.0 mol % phosphorous oxide. In otherembodiments, the bond material powder can be formed from less than about0.5 mol % phosphorous oxide. In particular instances, the bond materialpowder can be formed such that it is essentially free of phosphorousoxide.

Additionally, the bond material powder can be formed form particularcontents of boron oxide (B₂O₃), which may be lower than certainlow-temperature bond compositions. For example, the bond material powdermay contain less than 10 mol % boron oxide. In other instances, the bondmaterial powder can be formed from less than about 9.0 mol %, or evenless than 8.0 mol % boron oxide. Particular embodiments may utilize abond material powder formed from between about 5.0 mol % and about 10mol %, such as between about 5.0 mol % and 9.0 mol % boron oxide.

The bond material powder can include other materials, such as certainother metal oxide compounds or complexes. Suitable additional metaloxide compounds or complexes may include oxides of certain metalelements, such as transition metal species. Such metal oxide compoundsor complexes can include iron oxide, titanium oxide, zirconium oxide,zinc oxide, manganese oxide, cobalt oxide, chromium oxide, vanadiumoxide, bismuth oxide, and a combination thereof. The presence of suchadditional metal oxide species can be in minor amounts, such that thebond material powder contains less than about 2.0 mol %, and moreparticularly less than about 1.0 mol % of any one of the individualoxide compounds noted above.

After forming a mixture of abrasive grains in the bond material powder,it will be appreciated, that other materials may be added to themixture. For example, certain organic compounds may be added to themixture such as binders and the like to facilitate formation of thearticle. In accordance with one particular embodiment, the mixture cancontain a certain content of polyethylene glycol, animal glue, dextrin,maleic acid, latex, wax emulsion, PVA, CMC, and other organic and/orinorganic binder.

Additionally, other additives may be provided within the mixture tofacilitate formation of the final-formed bonded abrasive article. Forexample, some suitable additives can include pore formers including, butnot limited to, hollow glass beads, ground walnut shells, beads ofplastic material or organic compounds, foamed glass particles and bubblealumina, elongated grains, fibers and combinations thereof.

After forming the mixture at step 101, the process can continue at step103 by forming the mixture to form a green article. A green article isreference to an unfinished article which may not be thoroughly heattreated to complete densification (i.e. fully sintered). In accordancewith one embodiment, the process of forming the mixture can include apressing operation wherein the mixture is pressed into a particularshape similar to the shape of the intended final-formed bonded abrasivearticle. A pressing operation may be conducted as a cold pressingoperation. Suitable pressures can be within a range between about 10 andabout 300 tons.

After suitably forming the mixture at step 103, the process can continueat step 105 by heating the green article to a firing temperature of atleast 1100° C. to form the abrasive article. Firing is generally carriedout at a temperature suitable to form a vitrified bond material. Theforming processes of the embodiments herein utilize notably high firingtemperatures, such as at least about 1100° C. In other instances, thefiring temperature can be greater, such as at least about 1150° C., atleast 1200° C., at least about 1250° C., or even at least about 1300° C.The firing temperature used to form the bonded abrasive articles ofembodiments herein can be within a range between about 1100° C. andabout 1400° C., such as between 1100° C. and about 1300° C.

Generally, firing can be carried out in an ambient atmosphere, such thatis contains air. Generally, the duration of peak temperature for firingcan be at least about 1 hour, and particularly within a range betweenabout 1 to 10 hours. After sufficiently heating the article to form abonded abrasive article having abrasive grains contained within avitreous bond material, the article can be cooled. Embodiments hereinmay utilize a natural cooling process wherein the power to the furnaceis turned off and the article is allowed to cool from the firingtemperature to room temperature naturally.

As noted above, the bonded abrasive articles of embodiments herein caninclude abrasive grains contained within a bond material, wherein thebond material is a vitreous material having an amorphous phase.Moreover, the foregoing has noted particular contents of certaincompositions (e.g. alkaline oxide compounds, silica, alumina, boronoxide, etc), can change during the high temperature forming process suchthat the final-formed bonded abrasive article has a different content ofsuch compositions as compared to the content of such compositions withinthe initial mixture. Accordingly, the bonded abrasive articles ofembodiments herein are formed such that the final bond material of theabrasive article has certain contents of certain components and moreparticularly ratios of certain components such that the bonded abrasivearticle can be formed at high temperatures without severe degradationand dissolution of the microcrystalline alumina abrasive grains.

In particular, the final bond composition of the abrasive article canhave a particular content of alkali oxide compounds. For example, withrespect to sodium oxide, the bond material can contain not greater thanabout 8.0 mol % sodium oxide. In other embodiments, the amount of sodiumoxide can be less, such as not greater than about 7.0 mol %, or even notgreater than about 6.0 mol %. In particular instances, the bond materialcan contain between about 2.0 mol % and about 8.0 mol %, and moreparticularly between about 3.0 mol % and about 6.0 mol % sodium oxide.

With respect to potassium oxide, the bond material can contain at leastabout 4.0 mol % potassium oxide. In other instances, the bond materialcan contain at least about 5.0 mol % potassium oxide. In certainembodiments, the final bond material of the abrasive article can havebetween about 4.0 mol % and about 10 mol %, and particularly betweenabout 4.0 mol % and about 8.0 mol % potassium oxide.

Moreover, the final bond material of the abrasive article can be formedsuch that it has a particular ratio between the content of potassiumoxide and content of sodium oxide. For example, the ratio of potassiumoxide to sodium oxide in mol % and expressed as [K₂O/Na₂O] can have avalue that is greater than about 0.5. In other embodiments, the ratiocan be greater than about 0.75, such as greater than about 0.9, or evengreater than 1.0. Notably, the composition of the final bond materialcan utilize a ratio between potassium oxide and sodium oxide [K₂O/Na₂O]that is within a range between about 0.5 and about 2.2, such as betweenabout 0.75 and about 2.0, between about 0.8 and 1.9, or even betweenabout 1.0 and about 1.4.

As noted above, the initial mixture of the bond material can containparticularly low amounts of certain alkali oxide compounds such aslithium oxide. As such, the final-formed bond material of the abrasivearticle can generally have less than about 2.0 mol % lithium oxide, suchas less than 1.5 mol %, such as less than 1.0 mol %, or even less than0.5 mol % lithium oxide. Notably, in particular embodiments thefinal-formed bond material of the abrasive article can be essentiallyfree of lithium oxide.

The abrasive articles of embodiments herein can have a total content ofalkali oxide compounds that are significantly lower than otherconventional bond materials, which facilitates a bonded abrasive articleformed at high temperatures employing MCA grains with high integrity.That is, the total amount of alkali oxide compounds within the finalbond material can be less than about 13 mol %. In particular, the totalcontent of alkali oxide compounds can be less than about 12.8 mol %,less than about 12.6 mol %, less than about 12.4 mol % or even less thanabout 11.5 mol % for the total mols of material within the bondmaterial. In certain instances, the abrasive articles herein are formedsuch that the final bond material has a total content of alkali oxidecompounds that are less than 13 mol % and greater than about 8.0 mol %,such as less than about 12.8 mol % and greater than about 9.0 mol %, orless than about 12 mol % and greater than about 8 mol %, or less thanabout 11.5 mol % and about 9.0 mol %, and more particularly, less thanabout 11.5 mol % and greater than about 9.5 mol %.

The abrasive articles of embodiments herein can have a particularcontent of phosphorous oxide. For example, the final-formed bondmaterial can have less than about 1.0 mol % of phosphorous oxide, suchas less than about 0.5 mol % phosphorous oxide. In particular, thefinal-formed bond material of the abrasive article can be essentiallyfree of phosphorous oxide.

The final-formed bond of the abrasive articles of embodiments herein canhave a particular content of boron oxide. For example, the final-formedbond material can have less than 10 mol % boron oxide. In otherinstances, the final-formed bond material can contain less than about9.0 mol %, such as less than 8.0 mol % boron oxide. In certainembodiments, the final-formed bond material has a content of boron oxidewithin a range between about 1.0 mol % and about 10 mol %, such asbetween about 2.0 mol % and about 9.0 mol %, or even between about 2.0mol % and about 8.0 mol %.

In addition to the total content of boron oxide contained within thefinal-formed bond material, embodiments herein may utilize a particularratio between the content of boron oxide and other alkali oxidecompositions or even between the total content of boron oxide and totalcontent of alkali oxide compounds.

As will be appreciated, the bond material can contain a significantamount of silica. That is, the final-formed bond material can be formedsuch that it contains a majority amount of silica (i.e. greater than 50mol % silica). In other embodiments, the final-formed bond material cancontain greater than about 55 mol % silica, in particularly within arange between about 55 mol % and about 70 mol %, and more particularlybetween about 55 mol % and about 65 mol % silica.

Additionally, the final-formed bond material can exhibit a particularratio between the content of silica and total content of alkali oxidecompounds (C_(aoc)) measured in mol % and expressed as [C_(aoc)/SiO₂]and having a value greater than about 0.17. In other embodiments, theratio [C_(aoc)/SiO₂] can be greater than about 0.18, such as betweenabout 0.17 and 0.6, and particularly within a range between about 0.18and about 0.5.

The final-formed bond material can exhibit certain contents of alumina(Al₂O₃) suitable for forming the high-temperature bonded abrasivearticle. For example, the final bond material can contain at least about12 mol % alumina, such as at least about 13 mol % alumina, or even atleast about 14 mol % alumina. Still, the total content of alumina withinthe final bond may be limited, such as not greater than about 18 mol %,not greater than about 17 mol % or even not greater than about 16 mol %.As will be appreciated, the amount of alumina may be controlled incomparison to the total content of other species (i.e., oxide compounds)within the bond material, including, but not limited to, silica, alkalioxides, alkaline earth oxides, borides, and a combination thereof.

Additionally, the final-formed bond material may contain a certaincontent of alkaline earth oxide compounds (C_(aeoc)). Suitable alkalineearth oxide compounds can include magnesium oxide, calcium oxide,strontium oxide, and barium oxide. In particular instances, the abrasivearticle can be formed such that the final bond material can contain notgreater than about 6.0 mol %, such as not greater than about 5.0 mol %,or even, not greater than about 4.0 mol % magnesium oxide. In certainembodiments, the final-formed bond material contains between about 1.0mol % and about 6.0 mol %, such as between about 1.0 mol % and about 4.0mol % magnesium oxide.

Additionally, the final-formed bond material can contain a specificcontent of calcium oxide, particularly an amount that is less than thecontent of magnesium oxide. For example, the final-formed bond materialcan contain less than about 6.0 mol % calcium oxide, such as less thanabout 4.0 mol % calcium oxide, or even less than about 3.0 mol % calciumoxide. In certain embodiments, the final-formed bond material cancontain between about 1.0 mol % and about 5.0 mol %, such as betweenabout 1.0 mol % and about 3.0 mol % calcium oxide.

Moreover, the final-formed bond material can contain an amount of bariumoxide of less than about 2.0 mol %, such as less than about 1.0 mol %,and particularly within a range between about 0.1 and about 1.0 mol %.

The total content of alkaline earth oxide compounds (C_(aeoc)) can be atleast about 1.0 mol %, such as at least about 2.0 mol %, or even atleast about 3.0 mol %. Still, embodiments herein may utilize afinal-formed bond material that has a total content of alkaline earthoxides that is less than about 9.0 mol %, such as less than about 8.0mol %, or even less than about 7.0 mol %. That is, the final-formed bondmaterial of abrasive articles according to embodiments herein can have atotal content of alkaline earth oxides within a range between about 2.0mol % and about 9.0 mol %, such as within a range between about 3.0 mol% and about 7.0 mol %.

In addition to the total content of alkaline earth oxide compounds, thebond material may utilize a particular ratio between the total contentof alkali oxide compounds and alkaline earth oxide compounds. The ratiobetween the total content of alkali oxide compounds (in mol %) ascompared to the total content of divalent alkaline earth compounds (inmol %) can be a ratio expressed as [C_(aoc)/C_(aeoc)] having a value ofat least about 1.2. In other embodiments, this ratio can be at leastabout 1.5, such as at least about 1.75, at least 2.0. Still, the ratiocan be generally less than about 3.5, such as less than 3.25, and lessthan 3.0. Certain embodiments utilize a bond material having a ratio[C_(aoc)/C_(aeoc)] between the alkali oxide compounds and divalentalkaline earth compounds that is within a range between about 1.2 andabout 3.5, such as between about 1.5 and about 3.25, such as betweenabout 1.75 and about 3.0, and particularly within a range between about2.0 and about 2.75.

The compositions of the abrasive tools of the invention preferablycontain a total abrasive grain content from about 34 vol % to about 56vol %, such as between about 40 vol % and about 54 vol %, andparticularly between about 44 vol % and about 52 vol %. The MCA abrasivecan account for between about 1 to about 100 vol % of the total abrasivegrain of the abrasive article, such as between about 10 vol % and about80 vol %, or between 30 vol % and about 70 vol % of the total volume ofabrasive grain in the abrasive article.

The abrasive articles of the embodiments herein can include betweenabout 3.0 and about 30 vol % bond material. In more particularinstances, the abrasive article can contain between about 3 vol % toabout 25 vol % bond, between about 4 vol % to about 20 vol % bond, andeven between about 5 vol % to about 18.5 vol % bond. Moreover, someabrasive articles can include 0.1 vol % to 60 vol % of one or moresecondary abrasive grains, fillers and/or additives.

While a majority of the abrasive tools can have various degrees ofporosity, however, some of the abrasive bodies formed according toembodiments contained herein may exhibit a certain content of porosity.For example, the abrasive body can have a porosity that is less thanabout 50 vol % of the total volume of the abrasive body. In otherinstances, the porosity can be less than about 49 vol %, such as lessthan about 40 vol %. In particular instances, certain abrasive bodiescan be formed to have a porosity that is at least about 20 vol % andless than about 40 vol %, such as at least about 30 vol % and less thanabout 50 vol %, and more particularly between about 30 vol % and about49 vol %.

The abrasive articles described herein can be formed through ahigh-temperature forming process without particular dissolution ordegradation of the abrasive grains comprising the microcrystallinealumina. In particular, the abrasive bodies formed according to theprocesses herein can exhibit a particular hardness as measured in asandblast penetration test under the following conditions. Sandblasttests were conducted by first calibrating a standard, such as a glassplate material, on a table under a measuring rod and the standard wasplaced in contact with a surface of the blast seal. An air pressure of15 psi, in a chamber having a volume of 48 cc was used to blast standardgrade sand material at the surface of the standard (or samples) for asingle cycle time of 10 seconds. The depth of the hole formed in thestandard after a single cycle was measured and recorded. Upon confirmingthe depth of the hole formed in the standard was within the appropriaterange, samples formed according to embodiments herein were tested. Aswill be appreciated, the lower the value of the depth, the harder theabrasive article.

Certain abrasive articles of embodiments herein demonstrate a sandblastpenetration of not greater than about 2.2 mm. In fact, certain abrasivebodies exhibit a sandblast penetration of not greater than about 2.1 mm,such as not greater than about 2.0 mm, not greater than about 1.9 mm,not greater than about 1.8 mm, and even not greater than about 1.6 mm.

Example

Two samples were prepared, a sample S1 formed according to embodimentsherein and a second, conventional sample CS1 having a conventional bondmaterial. The samples S1 and CS1 were tested under particular grindingconditions to compare their performance properties.

The S1 sample was formed by initially combining 80-90 wt % of abrasivegrains with 9-15 wt % of an initial bond material having the compositionprovided in Table 1 below. The mixture further included a remainderamount (wt %) of other additives including a binder material. Sample 1was initially cold pressed to form a green article, and thereaftersintered at a firing temperature of about 1200° C. to form a finalbonded abrasive article having approximately 46-50 vol % abrasivegrains, 7-11 vol % bond material, and a reminder amount of porosity. Thefinal composition of the bond material is provided in Table 1.

TABLE 1 S1 Initial S1 Final Composition Composition Component (mol %)(mol %) SiO2 60.73 58.92 Al2O3 10.75 16.44 B2O3 7.97 7.45 Li2O 0 0 Na2O5.7 5.35 K2O 6.72 5.77 MgO 5.15 2.96 CaO 1.66 1.88 BaO 0.36 0.37 Fe2O30.18 0.1 TiO2 0.63 0.47 ZrO2 0.03 0.27 ZnO 0.12 0.02

The sample CS1 is formed according to the process of sample S1 having aninitial and final bond compositions as described herein. The CS1 samplewas fired at a firing temperature between about 900° C.-950° C. Likesample S1, the sample CS1 was formed such that it also containedapproximately 46-50 vol % abrasive grains, 7-11 vol % bond material, anda reminder amount of porosity.

The total alkali oxide compound content of the final-formed vitreousbond for the CS1 sample was approximately 16-18 mol % includingsignificant contents of lithium oxide, the total content of alkalineearth oxide compounds was approximately less than 1.5 mol %, the totalboron oxide content was greater than 10 mol % and calculated to bebetween about 14 and 18 mol %, the ratio between potassium oxide andcalcium oxide [K₂O/Na₂O] was between 0.01 and 0.05.

The samples S1 and CS1 were subject to an outer diameter (OD) plungegrinding test to determine the power consumption of the bonded abrasivearticles and also the final surface roughness of the test workpieceafter the grinding procedure. The OD plunge grinding conditions wereconducted under a controlled feed grinding condition using coolant, theconditions of which are summarized in Table 2 below.

TABLE 2 Parameter Values Workmaterial type 100Cr6 Wheel speed (m/sec) 35Table speed (mm/min) 200-1000 Depth of cut (mm) 1 Theoretical Material3.3, 6.7, 10, 13.3, 16.7 Removal Rate MRR (mm³/sec/mm) Grind Width (mm)10 Dressing Feed (mm/min) 835 Total dress amount (μm) 200

Table 3 below summaries the average power consumed during the grindingprocess for a given number of dressing cycles, and the roundnessdeviation of the workpiece after testing. As illustrated by the data,sample S1 demonstrated improved (i.e., lower) average power consumptionover the conventional sample, CS1, for a greater number of dressingcycles. Moreover, the roundness deviation of the workpieces ground bythe S1 samples were half of the roundness deviation of the samplesground using the CS1 bonded abrasive.

TABLE 3 Dressing Roundness Average Cycles (No. of Deviation Sample Power(mW) workpieces) (microns) CS1 5.8 10 20 S1 4.9 15 10

A second set of grinding tests were carried out using the samples S1 andCS1. Traverse surface grinding tests were conducted using the samples S1and CS1 using a coolant under conditions summarized in Table 4 below.

TABLE 4 Parameter Values Workmaterial type 100Cr6 Wheel speed (m/sec) 35Table speed (mm/min) 200-1000 Depth of cut (mm) 1 Theoretical Material3.3, 6.7, 10, 13.3, 16.7 Removal Rate MRR (mm³/sec/mm) Grind Width (mm)10 Dressing Feed (mm/min) 835 Total dress amount (μm) 200

The results of the testing are provided in plots of FIGS. 2 and 3. FIG.2 includes a plot of average power versus material removal rate (MMR)for the samples S1 and CS1. As indicated, the sample S1 demonstrated alower average power consumption over the range of tested materialremoval rates on the workpiece as compared to the sample CS1. Inparticular, at higher material removal rates exceeding 10 mm³/s/mm thedifference between the average power consumption of the sample CS1 andS1 was significant.

FIG. 3 is a plot of average surface roughness (Ra) of the workpiece asmeasured in microns versus the material removal rate for the samples S1and CS1. As illustrated in FIG. 3, generally the surface roughness ofthe workpiece after the grinding tests was approximately the same forboth samples. Notably, sample S1 was capable of providing nearly thesame surface roughness at high material removal rates as well as lowmaterial removal rates.

Notably, the combined information of FIGS. 2 and 3 indicates that thebonded abrasive article formed according to embodiments herein (SampleS1) can use less power even while utilizing increased material removalrates over a conventional sample. And additionally, even at highermaterial removal rates, the finish of the workpiece is not compromised.In fact, during testing, the workpieces ground using the sample CS1 wereburned, while the finish of the workpieces ground using the sample S1were not observed to be burned.

The embodiments herein are directed to abrasive articles incorporatingmicrocrystalline alumina grains in a high temperature bonded abrasivearticle, wherein the microcrystalline alumina grains exhibit improvedintegrity and minimized dissolution and degradation. State-of-the-artbonded abrasive articles employing MCA grains have been directed to theformation and use of low temperature vitrified bonds formed attemperatures below 1000° C. However, the embodiments herein are directedto a bonded abrasive article formed at high temperatures and use of abond material that facilitates high-temperature forming processes whileminimizing dissolution and degradation of the MCA grains. Theembodiments herein notably utilize one or more combination of features,including total contents of alkali oxide compounds, alkali earth oxidecompounds, boron oxide, silica, alumina, phosphorous oxide, and lithiumoxide, particular ratios of alkali oxide compounds, alkali earth oxidecompounds, boron oxide, silica, alumina, phosphorous oxide and lithiumoxide as compared to each other, and particular contents of abrasivegrains, bond, and porosity that facilitate the formation of a bondedabrasive article having improved characteristics, such as hardness andgrinding performance. The foregoing describes a combination of features,which can be combined in various manners to describe and define thebonded abrasive articles of the embodiments. The description is notintended to set forth a hierarchy of features, but different featuresthat can be combined in one or more manners to define the invention.

In the foregoing, reference to specific embodiments and the connectionsof certain components is illustrative. It will be appreciated thatreference to components as being coupled or connected is intended todisclose either direct connection between said components or indirectconnection through one or more intervening components as will beappreciated to carry out the methods as discussed herein. As such, theabove-disclosed subject matter is to be considered illustrative, and notrestrictive, and the appended claims are intended to cover all suchmodifications, enhancements, and other embodiments, which fall withinthe true scope of the present invention. Thus, to the maximum extentallowed by law, the scope of the present invention is to be determinedby the broadest permissible interpretation of the following claims andtheir equivalents, and shall not be restricted or limited by theforegoing detailed description.

The Abstract of the Disclosure is provided to comply with Patent Law andis submitted with the understanding that it will not be used tointerpret or limit the scope or meaning of the claims. In addition, inthe foregoing Detailed Description, various features may be groupedtogether or described in a single embodiment for the purpose ofstreamlining the disclosure. This disclosure is not to be interpreted asreflecting an intention that the claimed embodiments require morefeatures than are expressly recited in each claim. Rather, as thefollowing claims reflect, inventive subject matter may be directed toless than all features of any of the disclosed embodiments. Thus, thefollowing claims are incorporated into the Detailed Description, witheach claim standing on its own as defining separately claimed subjectmatter.

What is claimed is:
 1. An abrasive article comprising: an abrasive bodyhaving abrasive grains contained within a bond material, wherein theabrasive grains comprise microcrystalline alumina, and wherein the bondmaterial comprises less than about 1.0 mol % phosphorous oxide (P₂O₅),and a ratio between a total content of sodium oxide (Na₂O) measured inmol % and a total content of potassium oxide (K₂O) measured in mol %defined by [K₂O/Na₂O] having a value greater than about 1; wherein thebond material comprises a total content of alkali oxide compounds ofless than 12 mol %; and wherein the bond material comprises silica andwherein a ratio between a total content of silica (SiO₂) measured in mol% and a total content of alkali oxide compounds (C_(aoc)) measured inmol % expressed as [C_(aoc)/SiO₂] is greater than about 0.18.
 2. Theabrasive article of claim 1, wherein the ratio [K₂O/Na₂O] is within arange between about 1.0 to about 1.9.
 3. The abrasive article of claim1, wherein the bond material comprises less than about 0.5 mol %phosphorous oxide (P₂O₅).
 4. The abrasive article of claim 3, whereinthe bond material is free of phosphorous oxide (P₂O₅).
 5. The abrasivearticle of claim 1, wherein the bond material comprises less than about2.0 mol % lithium oxide (Li₂O).
 6. The abrasive article of claim 5,wherein the bond material is free of lithium oxide (Li₂O).
 7. Theabrasive article of claim 1, wherein the bond material comprises analkali oxide compound selected from the group of materials consisting ofpotassium oxide (K₂O), sodium oxide (Na₂O), and a combination thereof.8. The abrasive article of claim 7, wherein the bond material comprisesa total content of alkali oxide compounds of greater than about 9 mol %and less than about 11.5 mol %.
 9. The abrasive article of claim 1,wherein the ratio [C_(aoc)/SiO₂] is within a range between about 0.18and about 0.5.
 10. The abrasive article of claim 1, wherein the bondmaterial comprises not greater than about 8.0 mol % sodium oxide. 11.The abrasive article of claim 10, wherein the bond material comprisesbetween about 2.0 mol % and about 8.0 mol % sodium oxide.
 12. Theabrasive article of claim 1, wherein the bond material comprises atleast about 4.0 mol % potassium oxide.
 13. The abrasive article of claim12, wherein the bond material comprises between about 4.0 mol % andabout 10 mol % potassium oxide.
 14. The abrasive article of claim 1 inwhich the abrasive body has a porosity of less than about 50 vol %. 15.An abrasive article comprising: an abrasive body including abrasivegrains contained within a bond material, wherein the abrasive grainscomprise microcrystalline alumina, and wherein the bond materialcomprises less than about 2.0 mol % lithium oxide (Li₂O), and less thanabout 9 mol % boron oxide (B₂O₃), and wherein the bond materialcomprises between about 4.0 mol % and about 10 mol % potassium oxide.